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http://hdl.handle.net/2248/3494
Title: | Relativistic effective valence shell Hamiltonian method: Excitation and ionization energies of heavy metal atoms |
Authors: | Chaudhuri, R. K Freed, K. F |
Keywords: | Relativistic Corrections Excited States Hyperfine Structure Ionisation |
Issue Date: | May-2005 |
Publisher: | American Institute of Physics |
Citation: | Journal of Chemical Physics, Vol. 122, No. 20, pp. 204111 |
Abstract: | The relativistic effective valence shell Hamiltonian H(v) method (through second order) is applied to the computation of the low lying excited and ion states of closed shell heavy metal atoms/ions. The resulting excitation and ionization energies are in favorable agreement with experimental data and with other theoretical calculations. The nuclear magnetic hyperfine constants A and lifetimes tau of excited states are evaluated and they are also in accord with experiment. Some of the calculated uantities have not previously been computed. |
URI: | http://hdl.handle.net/2248/3494 |
ISSN: | 0021-9606 |
Appears in Collections: | IIAP Publications |
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Relativistic effective valence shell | 118.9 kB | Adobe PDF | View/Open |
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