Relativistic effective valence shell Hamiltonian method: Excitation and ionization energies of heavy metal atoms

dc.contributor.author	Chaudhuri, R. K
dc.contributor.author	Freed, K. F
dc.date.accessioned	2008-09-09T10:36:19Z
dc.date.available	2008-09-09T10:36:19Z
dc.date.issued	2005-05
dc.identifier.citation	Journal of Chemical Physics, Vol. 122, No. 20, pp. 204111	en
dc.identifier.issn	0021-9606
dc.identifier.uri	http://hdl.handle.net/2248/3494
dc.description.abstract	The relativistic effective valence shell Hamiltonian H(v) method (through second order) is applied to the computation of the low lying excited and ion states of closed shell heavy metal atoms/ions. The resulting excitation and ionization energies are in favorable agreement with experimental data and with other theoretical calculations. The nuclear magnetic hyperfine constants A and lifetimes tau of excited states are evaluated and they are also in accord with experiment. Some of the calculated uantities have not previously been computed.	en
dc.language.iso	en	en
dc.publisher	American Institute of Physics	en
dc.relation.uri	http://link.aip.org/link/?JCPSA6/122/204111/1	en
dc.relation.uri	http://dx.doi.org/10.1063/1.1906206	en
dc.subject	Relativistic Corrections	en
dc.subject	Excited States	en
dc.subject	Hyperfine Structure	en
dc.subject	Ionisation	en
dc.title	Relativistic effective valence shell Hamiltonian method: Excitation and ionization energies of heavy metal atoms	en
dc.type	Article	en