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Title: Relativistic equation-of-motion coupled-cluster method for the double-ionization potentials of closed-shell atoms
Authors: Pathak, H
Ghosh, A
Sahoo, B. K
Das, B. P
Vaval, N
Pal, S
Issue Date: Jul-2014
Publisher: The American Physical Society
Citation: Physical Review A, Vol. 90, No. 1, 010501
Abstract: We report the implementation of the relativistic equation-of-motion coupled-cluster method to calculate the double-ionization spectra (DI-EOMCC) of the closed-shell atomic systems. This method is employed to calculate the principal valence double-ionization potential values of He and alkaline-earth-metal (Be, Mg, Ca, Sr, and Ba) atoms. Our results are compared with the results available from the NIST database and other abinitio calculations. We have achieved an accuracy of ∼0.1%, which is an improvement over the first-principles T-matrix calculations [Y. Noguchi et al., J. Chem. Phys. 123, 144112 (2005)]. We also present results using the second-order many-body perturbation theory and the random-phase approximation in the equation-of-motion framework, and these results are compared with the DI-EOMCC results.
ISSN: 1094-1622
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Appears in Collections:IIAP Publications

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